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Preparation of sulfonated reduced graphene oxide by radiationinduced chemical reduction of sulfonated graphene oxide
Chang-Hee Jung, Ji-Hyun Hong, Jin-Mook Jung, In-Tae Hwang, Chan-Hee Jung and Jae-Hak Choi 한국탄소학회 Carbon Letters 4 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 6 41-44 (4 pages)
We report the preparation of sulfonated reduced graphene oxide (SRGO) by the sulfonation of graphene oxide followed by radiation-induced chemical reduction. Graphene oxide prepared by the well-known modified Hummer's method was sulfonated with the aryl diazonium salt of sulfanilic acid. Sulfonated graphene oxide (SGO) dispersed in ethanol was subsequently reduced by γ-ray irradiation at various absorbed doses to produce SRGO. The results of optical, chemical, and thermal analyses revealed that... -
Effect of surface treatment of graphene nanoplatelets for improvement of thermal and electrical properties of epoxy composites
Minjae Kim, Yeongseon Kim, Sung Hyeon Baeck and Sang Eun Shim 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 5 34-40 (7 pages)
is evaluated using transmission electron microscopy (TEM), scanning electron microscopy, thermogravimetric analysis, and energy dispersive X-ray spectroscopy. The electrical and thermal conductivities are characterized. The epoxy/silanized GNPs exhibits higher thermal and electrical properties than the epoxy/raw GNPs due to the improved dispersion state of the GNPs in the epoxy matrix. The TEM microphotographs and Turbiscan data demonstrate that the silane molecules grafted onto the GNP surface... -
Influence of hot-pressing pressure on the densification of short-carbon-fiber-reinforced, randomly oriented carbon/carbon composite
Thakur Sudesh Kumar Raunija and Sharad Chandra Sharma 한국탄소학회 Carbon Letters 9 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 4 25-33 (9 pages)
The prime objective of this research was to study the influence of hot-pressing pressure and matrix-to-reinforcement ratio on the densification of short-carbon-fiber-reinforced, randomly oriented carbon/carbon-composite. Secondary objectives included determination of the physical and mechanical properties of the resulting composite. The ‘hybrid carbon-fiberreinforced mesophase-pitch-derived carbon-matrix’ composite was fabricated by hot pressing. During hot pressing, pressure was varied from 5... -
Carbon nanotubes synthesis using diffusion and premixed flame methods: a review
Garima Mittal, Vivek Dhand, Kyong Yop Rhee, Hyeon-Ju Kim and Dong Ho Jung 한국탄소학회 Carbon Letters 10 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 1 1-10 (10 pages)
conventional methods. Flame synthesis is an energyefficient, scalable, cost-effective, rapid and continuous process, where flame provides the necessary chemical species for the nucleation of carbon structures (feed stock or precursor) and the energy for the production of carbon nanostructures. The production yield can be optimized by altering various parameters such as fuel profile, equivalence ratio, catalyst chemistry and structure, burner configuration and residence time. In the present... -
Effects of comonomer with carboxylic group on stabilization of high molecular weight polyacrylonitrile nanofibrous copolymers
Danyun Lei, Kesavan Devarayan1, Xiang-Dan Li, Woong-Ki Choi, Min-Kang Seo and Byoung-Suhk Kim 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 9 290-294 (5 pages)
New precursors, poly(acrylonitrile-co-crotonic acid) (poly(AN-CA)) and poly(acrylonitrile-co-itaconic acid-co-crotonic acid) (poly(AN-IA-CA)) copolymers, for the preparation of carbon fibers, were explored in this study. The effects of comonomers with acidic groups, such as crotonic acid (CA) and/or itaconic acid (IA), on the stabilization of nanofibrous polyacrylonitrile (PAN) copolymers were studied. The extent of stabilization, evaluated by Fourier transform infrared spectroscopy, revealed... -
Thermal properties in strong hydrogen bonding systems composed of poly(vinyl alcohol), polyethyleneimine, and graphene oxide
Sua Choi, Duck Kun Hwang and Heon Sang Lee 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 8 282-289 (8 pages)
Blends of poly(vinyl alcohol) (PVA), polyethyleneimine (PEI), and graphene oxide (GO) were prepared by solution casting method. Calorimetric thermal properties of the blends were investigated. The Tgs of PVA/PEI blends were higher than the Tgs of either of the component polymers at low concentrations of PEI. These abnormal increases of Tgs may be due to the negative entropy of mixing which is associated with strong hydrogen bonding between PVA and PEI. The degree of depression of s was not... -
Effects of phosphorus content and operating temperature on the electrochemical performance of phosphorus-doped soft carbons
Eun Hee Kim and Yongju Jung 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 7 277-281 (5 pages)
A series of high capacity soft carbons with different phosphorus contents were successfully prepared by carbonizing petroleum cokes treated with hypophosphorous acid at 900°C. The effect of phosphorus content on the electrochemical performance of the soft carbons was extensively investigated. The P-doped soft carbons exhibited greatly enhanced discharge capacities and outstanding rate capabilities with increasing phosphorus content. In addition, the influence of temperature on the... -
Novel reforming of pyrolized fuel oil by electron beam radiation for pitch production
Jin-Young Jung, Mi-Seon Park, Min Il Kim and Young-Seak Lee 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 5 262-267 (6 pages)
molecular weight, solubility, softening point, and density increased in proportion to the absorbed dose of E-beam radiation, with the exception of the highest absorbed dose, due to modification by free radical polymerization and the powerful energy intensity of E-beam treatment. The H/C ratio and yield exhibited the opposite trend for the same reason. These results indicate that novel E-beam radiation reforming is suitable for the preparation of aromatic pitch with a high β-resin content. -
Modification of isotropic coal-tar pitch by acid treatments for carbon fiber melt-spinning
Mi Jung Yoo, Hyo Jun Ko, Yun-Soo Lim and Myung-Soo Kim 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 3 247-254 (8 pages)
In this work, thermal treatment accompanied with different acid treatments was applied to a commercial coal tar pitch (CTP) to obtain a spinnable precursor pitch for carbon fiber. In the case of thermal treatment only, a relatively high reaction temperature of between 380°C and 400°C was required to obtain a softening point (SP) range of 220°C-260°C and many meso-phase particles were created during the application of high reaction temperature. When nitric acid or sulfuric acid treatment was... -
Overlook of carbonaceous adsorbents and processing methods for elemental mercury removal
Kyong-Min Bae, Byung-Joo Kim and Soo-Jin Park 한국탄소학회 Carbon Letters 9 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 2 238-246 (9 pages)
People have been concerned about mercury emissions for decades because of the extreme toxicity, persistence, and bioaccumulation of methyl Hg transformed from emitted Hg. This paper presents an overview of research related to mercury control technology and identifies areas requiring additional research and development. It critically reviews measured mercury emissions progress in the development of promising control technologies. This review provides useful information to scientists and engineers...


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