- Ethylenediamine 鹽酸鹽의 結晶構造
- ㆍ 저자명
- 구정회,김문일,유정수,Koo. Chung Hoe,Kim. Moon Il,Yoo. Chung Soo
- ㆍ 간행물명
- 대한화학회지
- ㆍ 권/호정보
- 1963년|7권 4호|pp.293-298 (6 pages)
- ㆍ 발행정보
- 대한화학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The crystal structure of ethylenediamine dihydrochloride has been determined by the two-dimensional Patterson methods and refined by two-dimensional Fourier syntheses. The unit cell dimensions are a = 4.44${pm}$0.02, b = 6.88${pm}$0.02, c = 9.97${pm}$0.02 ${AA}$, ${eta}$ = 92${pm}$$1^{circ}$. The space group is $P2_1_{/c}$. The carbon and nitrogen atoms in the ethylenediamine itself lie on one plane and its structure has a trans-form with a centre of symmetry in it, and C-C distance of 1.54 ${AA}$, C-N distance of 1.48${AA}$ and C-C-N bond angle of $109.07^{circ}$. The molecules are linked by N-H${cdots}$Cl hydrogen bonds with distance of 3.14, 3.16 and 3.22 ${AA}$ forming three dimensional network. The values of reliability factor for F(okl), F(hol) and F(hko) are 0.11, 0.10 and 0.09 respectively.