- 熱力學函數間의 直線關係 第四報 Dimethylaniline 直換體의 鑒基度에 關한 硏究
- ㆍ 저자명
- 이익춘,박용자,Lee. Ik-Choon,Park. Yong-Ja
- ㆍ 간행물명
- 대한화학회지
- ㆍ 권/호정보
- 1964년|8권 1호|pp.15-19 (5 pages)
- ㆍ 발행정보
- 대한화학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
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Basicities of nine dimethylanilines have been determined in 50, 70, and 90 volume % ethanol, at $25^{circ},;30^{circ},;35^{circ},;and;40^{circ}C$. Temperature coefficients were found to be independent of solvent composition, while they showed a linear correlation with basicities of the compounds. Thermodynamic parameters obtained have been used in the discussion of substituent and solvent effects in conjunction with the general equation derived in the preceding papers.