- Al의 양극처리에 관한 연구 (제1보) (전해조건이 피막에 미치는 영향)
- ㆍ 저자명
- 이종남,이성주,김회정
- ㆍ 간행물명
- 금속표면기술
- ㆍ 권/호정보
- 1967년|1권 1호|pp.14-15 (2 pages)
- ㆍ 발행정보
- 한국표면공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The characteristics of sulfuric acid anodized layer was studied under various Conbitions, acid concentration : 5-20%, temperature : 5-25$^{circ}C$, bath voltate : 16 volts , bath agitain : mech agitation : mechanical . The Al+++ ion increase in anodizing baty, the film thickness under microscope, the comparative porosity and the thickness were determined. It was found that film thickness and the porosithy which are the main factors of determining andoized layet quality, rule the corrosing and abrasiion tesistance of the film, and that the porosity is increasing in the outerlayer. The formation mechanism was assumed as follows : The film thickness -increase is due to OH_ ion diffusion into compact non-conductive layer and Al+ + OH_ longrightarrowAl(OH), Al(OH)+ + OH_ longrightarrowAl(OH)+$_2$ , Al(OH)+$_2$ + OH_ longrightarrowAl(OH)$_3$., the strong adhesion force is alse due to Al(OH) or Al(OH)$_2$ in transtion layer. And the pore-nucleation is produced by volume change between Al and Al$_2$O$_3$ and activated H$_2$O gas created by large reaction heat of Al+(x) +OH_ longrightarrowAl(OH)x.