- Cyclitol 유도체 합성에 관한 연구 (제4보) DL-epi-inosose-2의 전해환원
- ㆍ 저자명
- 손주환,남종우,박흥조,Sohn. Joo-Hwan,Nam. Chong-Woo,Park. Heung-Cho
- ㆍ 간행물명
- 대한화학회지
- ㆍ 권/호정보
- 1972년|16권 2호|pp.93-99 (7 pages)
- ㆍ 발행정보
- 대한화학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
To obtain the various kinds of inositol stereomers, we have selected the process of electrolytic reduction of DL-epi-inosose-2 using Ni, Ta, Cu, Mo, Pb, Sn, W, Cd and Hg etc., as cathode. We think that this process gives greater variety than chemical processes. DL-epi-inosose-2 was synthesized by chemical oxidation of myo-inositol, dissolved in aqueous solution of potassium hydroxide, and used as electrolytic solution. To prevent anodic oxidation of cathode products the H-type diaphragm cell was used. As the results of paper chromatography of cathodic products, we obtained the $R_f$ values of myo-inositol and epi-inositol were in good agreement with literature values.