기관회원 [로그인]
소속기관에서 받은 아이디, 비밀번호를 입력해 주세요.
개인회원 [로그인]

비회원 구매시 입력하신 핸드폰번호를 입력해 주세요.
본인 인증 후 구매내역을 확인하실 수 있습니다.

회원가입
서지반출
동염존재하의 견사에 대한 graft 공중합에 있어서의 중합도
[STEP1]서지반출 형식 선택
파일형식
@
서지도구
SNS
기타
[STEP2]서지반출 정보 선택
  • 제목
  • URL
돌아가기
확인
취소
  • 동염존재하의 견사에 대한 graft 공중합에 있어서의 중합도
  • Degree of Polymerization of Graft Copolymers of Methyl Methacrylate on Silk in the Presence of Cupric Salt
저자명
신현우
간행물명
韓國纖維工學會誌
권/호정보
1973년|10권 3호|pp.1-6 (6 pages)
발행정보
한국섬유공학회
파일정보
정기간행물|
PDF텍스트
주제분야
기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

The degree of polymerization of the PMMA contained in the silk fibre, which was obtained by graft copolymerization by using Cu(II)/H$_2$O$_2$as an initiator was studied under the various conditions of polymerization. For both the grafted PMMA and free PMMA formed out side the silk fibre, the degrees of polymerization were found as follows. (1) The degree of polymerization was roughly proportional to the concentration of monomer. (2) With increasing concentration of cupric salt, the degree of polymerization was decreased gradually. (3) The effect of hydrogen peroxide on the degree of polymerization was considerable, and D.P. has a maximum value at concentration of 10-$^1$mole/l and the curve of degree of polymerization was similar to that of graft-on. (4) The maximum value of graft-on and that of the degree of polymerization were at 30 min. 70$^{circ}C$. The value of graft-on after 30 min. was steady, however, the degree of obtained polymerization was decreased. (5) The degree of polymerization was affected considerably by the temperature of the polymerization and its maximum value was attained at 70$^{circ}C$ as in graft-on. (6) The degree of polymerization of the graft PMMA is generally larger than that of the free PMMA outside of the fibre.