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2-Methoxy-5-Nitrophenol 금속착염의 화학적 성질에 관한 연구
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  • 2-Methoxy-5-Nitrophenol 금속착염의 화학적 성질에 관한 연구
저자명
김선덕,우세홍,김명운
간행물명
한국환경위생학회지
권/호정보
1974년|1권 1호|pp.21-27 (7 pages)
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한국환경보건학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

This work was carried out to investigate the chemical properties of the chelate compounds which were produced with 2-methoxy-5-nitrophenol(MNG) and metal salt such as copper nitrate and manganese nitrate. And obtained results were as in the followings. 1) The binding ratio of the chelate compounds formation were determined by using the molar ratio concentration method and their chemical structures were identified by IR-spectrum. 2) In the absorbance measuring, 2-methoxy-5-nitrophenol coordinated with manganese and copper showed the maximum absorbance at $430 mmu$ and $410 mmu$ respectively. 3) The binding ratio of chelated compounds were measured by molar ratio method and continuous variation method with spectrophotometer, which was identified as 1:2. 4) The conditional formation constant(log Kn value) of manganese and copper chelate compounds were 6.70, 6.75, respectively according to the equation of $logfrac{A-AMcirc n MNG}{AMm MNG-A}=n log (Mcirc)+log Kn$ 5) The dissociations degree of manganese and copper chelate compound were $2, 300{ imes} 10^{-7}$, $2, 346{ imes} 10^{-7}$ respectively according to the molar calculation method.