This study investigated the deterioration phenomena of the Polyethylene surface contaminated with organic(Saccharose) or inorganic(NaCl) matters through electrical and optical experiments. And also these experimental results relatively well coincided with which was treated by theoretical process. On the electrical experiment, relation between electric field intensity in corona discharge and time reached to the breakdown, and relation between total amount of charges discharged and increment of applied voltage were investigated. On the optical experiment, discharge time dependence of surface deterioration rate and process of surface deterioration in the X-ray diffraction pattern were investigated. It was concluded that chemical effects by the corona discharge deteriorated insulation characteristics of Polyethylene surface.