- 가열속도법에 의한 반응속도론 연구
- Kinetic Study by Heating Rate Method
- ㆍ 저자명
- 박영수,양광규,김용태
- ㆍ 간행물명
- 한국연초학회지
- ㆍ 권/호정보
- 1982년|4권 2호|pp.57-61 (5 pages)
- ㆍ 발행정보
- 한국연초학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
For evaluating kinetic parameters of various reactions and materials a straight- forward method has been studied by the variable heating rate method in DSC analysis. Based on the linear relationship between the logarithm of the heating rate and reciprocal Peak temperature, this method allows calculation of activation energy and the Arrhenius frequency factor by only one observation of the peak temperature versus the heating rate. According to tile D function, D=-In P(x)/dx, to x(=$frac{E}{RT}$) we can calculate reasonably accurate activation energy, tile Arrhenius factor and the rate constant, and predict half-life times of various materials from the kinetic calculation.