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The Swelling and Mechanical Properties of Hydrogels of Tactic Poly (2-Hydroxyethyl Methacrylate)
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  • The Swelling and Mechanical Properties of Hydrogels of Tactic Poly (2-Hydroxyethyl Methacrylate)
저자명
Lee. Joong-Whan,Kim. Eul-Hwan,Jhon. Mu-Shik
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1983년|4권 4호|pp.162-169 (8 pages)
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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The swelling and stress-elongation experiments have been performed for two kinds of gels of tactic poly (2-hydroxyethyl methacrylate) (P-HEMA) with varying crosslinker concentrations. The gels of isotactic and syndiotactic P-HEMA were swollen in aqueous salt solutions upon varying molal concentrations. The solute used were NaCl, $MgCl_2$, $Na_2SO_4$, $MgSO_4$ and urea. The water content at equilibrium swelling and the salt partition coefficient were determined, and stress-elongation curves of the gels were obtained. From these results, the effective number of chain (${ u}_e$) and the Flory-Huggins interaction parameter (${chi}_1$) were also obtained. The swelling experiment was also performed under varying solvents, and the degree of swelling was determined. The solubility parameter of P-HEMA was obtained as 13.4 (cal/mole)$^{l/2}$ using the correlation between the degree of swelling and the solubility parameter (${delta}_1$) of solvents. The mechanical properties of syndiotactic P-HEMA is stronger than that of isotactic P-HEMA, and the water content of both gels become smaller when the crosslinking increases. Isotactic P-HEMA contains more water content than syndiotactic P-HEMA does.