- 조립자규소 성형체의 효과적 질화가열법에 관한 연구(Densification of Silicon Nitride 3보)
- ㆍ 저자명
- 박금철,최상욱
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1984년|21권 1호|pp.33-40 (8 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
To find out the optimum heating profile for the nitridation of compacts of graded silicon grains (max 53$mu extrm{m}$) two batches with the addition of MgO and $Mg(NO_3)_3$$cdot$$6H_2O$ to silicon particles were isostatically pressed into compacts. They were nitrided under some different nitriding schedules. The properties such as bulk densitis microstructures and formed phases were measured and observed. The following results were obtained ; 1) About 10% unreacted silicon remained in specimen which was nitrided at 1, 350$^{circ}C$ for 240hrs. 2) One of the step-heating processes 1, 150$^{circ}C$</TEX>-1, 390$^{circ}C$ for 65hrs are then $1, 390^{circ}C$for 50hrs was the low temperature but with that at high temperature. 3) High pressure(10.5kgf/$cm^2$) of nitrogen at 1, 390$^{circ}C$</TEX> accelerated the $alpha$<TEX>$ ightarrow$</TEX>$eta$ transformation of silicon nitride. 4) Magnesium nitrate was superior to magnesium oxide in the role of nitriding aid and the formation of uniform microstructures.