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The trans $ ightarrow$ cis Photoisomerization and Fluorescence of trans 1,2-Bispyrazylethylene: pH, Salt and Heavy Atom Effects
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  • The trans $ ightarrow$ cis Photoisomerization and Fluorescence of trans 1,2-Bispyrazylethylene: pH, Salt and Heavy Atom Effects
  • The trans $ ightarrow$ cis Photoisomerization and Fluorescence of trans 1,2-Bispyrazylethylene: pH, Salt and Heavy Atom Effects
저자명
Shim. Sang-Chul,Bong. Pill-Hoon
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1986년|7권 1호|pp.53-55 (3 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The $trans{ ightarrow}cis$ photoisomerization and fluorescence of trans-1,2-bispyrazylethylene were investigated in various conditions. The quantum yields of the $trans{ ightarrow}cis$ photoisomerization and the fluorescence intensity of trans-1,2-bispyrazylethylene decrease on going from neutral to acidic or basic solutions. The quantum yields of photoisomerization, however, are little affected by changing the concentration of salt while the fluorescence intensity increases as the concentration of salt increases. pH and salt effects on the energy levels of $^1(n,;{pi}^*);and;^1({pi},; {pi}^*)$ states lead to opposing changes in photoisomerization and fluorescence quantum yields. The heavy atom effect on the fluorescence of 1,2-bispyrazylethylene was also investigated.