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Crystal Structure of Fully Dehydrated Partially Ag$^+$-Exchanged Zeolite 4A, $Ag_{7.6}Na_{4.4}$-A. Ag$^+$ Ions Prefer 6-Ring Sites. One Ag$^+$ Ion is Reduced
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  • Crystal Structure of Fully Dehydrated Partially Ag$^+$-Exchanged Zeolite 4A, $Ag_{7.6}Na_{4.4}$-A. Ag$^+$ Ions Prefer 6-Ring Sites. One Ag$^+$ Ion is Reduced
  • Crystal Structure of Fully Dehydrated Partially Ag$^+$-Exchanged Zeolite 4A, $Ag_{7.6}Na_{4.4}$-A. Ag$^+$ Ions Prefer 6-Ring Sites. One Ag$^+$ Ion is Reduced
저자명
Kim. Yang,Han. Young-Wook,Seff. Karl
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1986년|7권 3호|pp.190-193 (4 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The structure of partially $Ag^+$-exchanged zeolite 4A, $Ag_{7.6}Na_{4.4}-A$, vacuum dehydrated at $370^{circ}C$, has been determined by single-crystal x-ray diffraction techniques in the cubic space group, Pm3m (a = 12.311(1)${AA}$) at $24(1)^{circ}}C$. The structure was refined to the final error indices $R_1$ = $R_2$ (weighted) = 0.064 using 266 independent reflections for which $I_0$>$3{sigma}(I_0)$. Three $Na^+$ ions occupy the 3 8-ring sites, and the remaining ions, 1.4 $Na^+$ and 6.6 $Ag^+$, fill the 8 6-ring sites; each $Ag^+$ ion is nearly in the [111] plane of its 3 O(3) ligands, and each $Na^+$ ion is 0.9${AA}$ from its corresponding plane, on the large-cavity side. One reduced silver atom per unit cell was found inside the sodalite unit. It was presumably formed from the reduction of a $Ag^+$ ion by an oxide ion of a residual water molecule or of the zeolite framework. It may be present as a hexasilver cluster in 1/6 of the sodalite units, or, most attractively among several alternatives, as an isolated Ag atom coordinated to 4 Ag ions in each sodalite unit to give $(Ag_5)^{4+}$, symmetry 4mm.