- 1,1-Dimethyl-2,5-bis(trimethylsilyl)-3,4-diphenyl-1-silacyclopenta-2,4-diene의 합성
- ㆍ 저자명
- 공영건,주완철,Kong. Young Kun,Joo. Wan-Chul
- ㆍ 간행물명
- 대한화학회지
- ㆍ 권/호정보
- 1986년|30권 6호|pp.521-525 (5 pages)
- ㆍ 발행정보
- 대한화학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Phenyltrimethylsilylacetylene과 리듐의 반응으로 부터 1,4-bis(trimethylsilyl)-2,3-diphenyl-1,4-butadene dianion이 형성되었다. 이 반응생성물과 dichlorodimethylsilane을 반응시키면 1,1-dimethyl-2,5-bis(trimethylsilyl)-3,4-diphenyl-1-silacyclopenta-2,4-diene이 얻어졌다. 이와 함께 분리된 1,4-bis(trimethylsilyl)-2,3-diphenyl-1,3-butadiene은 알칼리 매질에서 가수분해되어 생성된 화합물로 보인다
From the reaction of phenyltrimethylsilylacetylene with lithium, 1,4-bis(trimethylsilyl)-2,3-diphenyl-1,4-butadene dianion was formed. The reaction of dianion with dichlorodimethylsilane affords 1,1-dimethyl-2,5-bis(trimethylsilyl)-3,4-diphenyl-1-silacyclopenta-2,4-diene. In addition 1,4-bis(trimethylsilyl)-2,3-diphenyl-1,3-butadiene was isolated. It seems to be hydrolized product in alkali medium