The characteristics of arc sprayed layer were studied with hardness test and microstructural observation. The erosion resistance of arc sprayed layer was also evaluated using a method of steel ball blasting test which was proposed in this study as a test method for measuring the erosion properties in the impact wear condition. By an impact of the molten droplets on the redeposited substrate, lamella structure was formed which contains laminated oxide layers, fissures, and porosities. As a result of mechanical tests, it was shown that the sprayed specimen showed higher hardness than the substrate, but it resulted in higher erosion rate than the substrate. The poor erosion property obtained with a sprayed coating was considered to be attributable to easy flaking off the the layers laminated with brittle oxide layers.