Interfaces, both grain boundaries and phase boundaries, play a very important role in the mechanical behavior of structural materials. The problemis particularly intense in composite materials where interfaces play a primary role in the meehanical response of the composites. This paper will concentrate on the approaches to perform nondestructive evaluation of the interfaces in a man nor in which some measure of the mechanical behavior of the interface can be established. Some of the possible approaches that may have potential for the nondestructive evaluation of interfaces are optical, electronic/ electrical, and acoustic approaches.