After Ba-ferrite powders synthesized hydrothermally and its heated powders were dissolved partially with HCl treatment time, the BaO/Fe2O3 mole ratio of dissolved solutions and powders were measured by AAS, also, lattice constants, particle morphology and magnetic properties in HCl treated, heated and no-heated Ba-ferrite powders were abtained by means of XRD, SEM and VSM, respectively. From above analysis results, the effect of Ba/Fe mole ration in suspension(as starting material) on the BaO/Fe2O3 composition and particle characteristics of products were investigated, and the effect of heat treatment on magnetic properties of products examined. The composition, lattice constant and crystal phase of products depend on the Ba/Fe mole ratio in suspension. Ba content in surface or outer part of Ba-ferrite powder is higher than inner and heterogeneous, and the excess Ba ions in the inner part of particle move into the outer by heating, so that the mole ratio of BaO/Fe2O3 in the more jinner approaches more to the stoichiometric composition 1 : 6. The crystallinity, coercivity and saturation magnetization of products are increased by heat treatment, and the heat-treated samples synthesized hydrothermally in lower temperature are appreciated to have better powder characteristics.