With reference to the Spread Spectrum techniqeu diseussed and further extended by many investigators, the Peseudo-noise Code Polarity Modulation (PNCPM) technique has proposed in this paper. By using this new technique of PNCPM, some problems pertaining to the Spread Spectrum mode has been sloved. In addition by the PNCPM mode it is proposed that data shifting can be easily demodulated every clock(frame) by measn of simple hardware implementaton for the purpose of operating of the asynchroniged detection mode. And in this paper it is shown that PNCPM mode can be easily implemented by the CCD correlator, and is applicable to the Spread Spectrum Multiple Access.