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Potential Profiles and Capacitances of an Ideally Polarizable Electrode in a point Charged Electrolyte
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  • Potential Profiles and Capacitances of an Ideally Polarizable Electrode in a point Charged Electrolyte
  • Potential Profiles and Capacitances of an Ideally Polarizable Electrode in a point Charged Electrolyte
저자명
Kim. Sang youl,Vedam. K.
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1989년|10권 6호|pp.585-591 (7 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The effects of the charged metal on the overall electrostatic potential profiles and the capacitances of the electrical double layer are brought out. A model with a simplified jellium and a point-charged electrolyte is utilized in the present calculations. Electrons are assumed not to penetrate electrode surface due to a strong screening of electrolyte at the interface. Electron density functions and ion density functions are obtained, which are also based upon the Poisson equation and Boltzmann equation on either side of the interface. A complete potential profile starting from bulk electrode and ending at bulk electrolyte is obtained by connecting the two potential profiles (one inside the metal electrode, the other inside the electrolyte) with proper boundary conditions. In spite of the simplicity of the model, the present model reveals the importance of the effect of the charged metal on the electrostatic potential profile and the electrical double layer capacitances. The results are discussed and compared with the predictions by Gouy Chapman theory.