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고무물성(物性)에 미치는 국산(國産) 무기충전제(無機充塡劑)의 효과(效果)에 관(關)한 연구(硏究)
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  • 고무물성(物性)에 미치는 국산(國産) 무기충전제(無機充塡劑)의 효과(效果)에 관(關)한 연구(硏究)
  • A Study on Effect of Inorganic Fillers to Rubber Properties
저자명
김기주,김종석,안병국,서수교,장영재,강경호,Kim. Ki-Joo,Kim. Jong-Seok,Ahn. Byung-Kook,Suh. Soo-Kyo,Chang. Young-Jae,Kang. Kyoung-Ho
간행물명
고무學會誌
권/호정보
1989년|24권 4호|pp.276-289 (14 pages)
발행정보
한국고무학회
파일정보
정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

This study deals with both effects of inorganic fillers to vulcanized rubbers such as NR, CR, EPDM, NBR & SBR and inorganic characteristics of domestic fillers in comparision with hard clay produced in the USA. The results were as follows. 1. Main ingredient of domestic clay "Ha-dong clay" was Halloysite, "No-ha Island" was Pyrophyllite with $alpha$-Quartz, and both of "Hard clay" & "Hwa-soon clay" were proved to be Kaolinite by XRD, DT-TGA and chemical analysis by XRF. 2. Tensile strength value of SBR compounded with these fillers, was Hard clay $146kg;f/cm^2$, Kaolinite $123kg;f/cm^2$, Pyrophyllite $82kg;f/cm^2$, Halloysite $80kg;f/cm^2$, precipitated $CaCO_3;27kg;f/cm^2$, and ground $CaCO_3$ was $21kg;f/cm^2$. These results showed the increase of seven times according to filler species. 3. The physical properties of non-crystalline rubbers, such as SBR, NBR & EPDM, compared with NR & CR, have been considerably changed according to crystalline phase, particle size, shape and surface structure of fillers. Especially, tensile strength value in case of SBR & EPDM, was differentiated about 1.5 times by the particle size of fillers. 4. In SBR, physical properties of rubber compounded with Kaolinite which was surface treated with fatty acid and silane, almost approach to the value of hard clay. 5. Delayed cure time of Kaolinite and decrease of rubber properties by $CaCO_3$ can be improved by blending kaolinite & $CaCO_3$ in the ratio of 2:1.