DC potential drop(DCPD) measurement system was made and the optimum measuring conditions have been studied. The room temperature resistivity of commercially available medium carbon steel(S45C) was measured using this technique. DCPD was measured in the specimens which were hardened and tempered at different temperatures. It was found that DCPD reflected the change of the microstructure during tempering very sensitively. It was possible to monitor the stage of tempering of S45C steel nondestructively using DCPD measurement.