A rapid expansion of moist air of condensible gas through a supersonic nozzle gives rise to condensation of nonequilibrium and equilibrium processes. Because most of the effects of condensation on the flow are caused by process of nonequilibrium condensation, it is very important to know the onset. condition of nonequilibrium condensation. In the present study, the relation between the initial relative stagnation humidity and the onset Mach number, for the case of the similarity law suggested by Zierep and Lin. Furthermore, the present theoretical result number is compared with the experimental, numerical and other results.