- PET/PPG 공중합체의 핵제 첨가에 따른 결정화 거동
- The Effect of Nucleating Agent on the Crystallization of PET/PPG Copolymer
- ㆍ 저자명
- 최재호,조순채
- ㆍ 간행물명
- 韓國纖維工學會誌
- ㆍ 권/호정보
- 1990년|27권 10호|pp.28-40 (13 pages)
- ㆍ 발행정보
- 한국섬유공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The crystallization behaviours from the glassy state and the melt of PET/PPG copolymer filled with additives were investigated . The overall rate of crystallization was measured by differential scanning calorimetry and the increase of density of the samples measured by the buoyancy method, was used to follow the crystallization progress. The results were analyzed by the crystallization parameters Tcc (crystallization temperatures from the melt state), Tch (crystallization temperatures from the glassy state), Tcc-Tch, Tm-Tcc (Tm : melting temperature), half time of crystallization, rate constant, Avrami exponent, degree of crystallization. Talc, kaolin, TiOa, crystalline SiOa, amorphous SiOa, and Cac03 were used as fillers and sodium stearate and tritolyl phosphate used as lubricant. The filler and the lubricant acting as most effective nucleating agents for PET/PPG copolymer were talc and sodium stearate and their suitable contents were 0.6 nVo and 0.3 wt% per weight of copolymer, respectively. Tcc-Tch values of PET/PPG copolymer were lower than them of PET, but the values of the copobymer filled with additives were much greater than PET filled with them. It has found that the crystalliration rate has been greatly increased by combining the factors acting as effective increase of crystallization rate.