The resistivity of cement paste and mortar for freezing and thawing was investigated for densifying the structure of cement paste and mortor, slag, diatomaceous earth and fly ash as blending materials and superplasticizer were used, and air entraining agent was added to absorb the volume expansion by freezing and thawing reaction. And then the specimens were subjected to freeze-thaw in water. When both of air entraining agent and superplasticizer as additives were mixed to specimens, their freeze-thaw resistance was enhanced by the air entraining effect and the water reduction effect. When 4% of slag were added to cement, freeze-thaw resistance was especially excellent. In addition, it was found that the specimens with blending materials were more influenced by curing periods than those without admixture. It is assumed that the curing periods contribute to exibit the potential hydraulicity and pozzolanic reactivity of blending materials and to densify their texture.