The purpose of this study is to investigate electrostatic charge condition and possibility of electrostatic hazards in case of putting on synthetic smocks and antistatic garments for the purpose of prevention of electrostatic hazards due to a human body electrical charge. It is shown in case of a synthetic smocks, electrostatic voltage by friction is about 2,900 (V), half life period is 12 second, and electrostatic charge is 1.4―1.8 ($mu$ C). When putting on a synthetic smocks, electrostatic voltage is 2,500―2,800(V). When putting on a jumper of chemical fiber, electrostatic voltage is 8,000(V) . It is, therfore, possible to cause a electrostatic hazards. It is also shown in case of a antistatic garments, electrostatic voltage by friction is 87(V) ―280(V) (washing 90 times), half life period is 3―5 second, and electrostatic charge is 0.24―0.28($mu$ C) which is much lower than 0.6($mu$ C) limitation of fire and explosion occurance. When putting on a antistatic garments, electrostatic voltage is 10(V) ―125(V). In conclusion, it is shown when putting on a antistatic garments it is possible to prevent a electrostatic hazards such as fire or explosion due to human body, to prevent a destruction of semiconductor elements and capacity decline, and to prevent a misoperation of automation facilities and semiconductor electric and electronic products.