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$CO_2$ Laser Induced Decomposition of 1-Bromo-3-Chloropropane
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  • $CO_2$ Laser Induced Decomposition of 1-Bromo-3-Chloropropane
  • $CO_2$ Laser Induced Decomposition of 1-Bromo-3-Chloropropane
저자명
Chun. Byoung Soo,Song. Nam Woong,Choo. Kwang Yul
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1990년|11권 3호|pp.214-220 (7 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

We have studied the Infrared Multiphoton Dissociation (IRMPD) of 1-bromo-3-chloropropane by using the pulsed $CO_2$ laser. The product yields and the HCl/HBr branching ratios in IRMPD of $BrCH_2CH_2CH_2Cl$ are studied under the focused beam geometry as a function of buffer gas (He) pressure, laser energy, and photolysing wavelength. It is observed that the total dissociation yield has a laser energy dependence of 1.8-2.0 power order and the branching ratio is very slightly dependent on the pulse energy for the laser lines employed. The dependences of total dissociation yield and branching ratio on the buffer gas pressures show that the dissociation yield monotonically decreases and the branching ratio slightly decreases with the increase of the buffer gas pressure. The Energy-Grained Master Equation (EGME) was applied to explain the laser pulse energy and the buffer gas pressure(He) dependence of the dissociation yield and the branching ratio.