A wave instability problem is formulated for natural convection flows adjacent to a inclined isothermal surface in pure water near the density extremum. It accounts for the nonparallelism of the basic flow and temperature fields. Numerical solutions of the hydrodynamic stability equations constitute a two-point boundary value problem which are accurately solved using a computer code COLSYS. Neutral stability results for Prandtl number of 11.6 are obtained for various angles of inclination of a surface in the range from-10 to 30 deg. The neutral stability curves are systematically shifted toward modified Grashof number G=0 as one proceeds from downward-facing inclined plate(.gamma.<0.deg.) to upward-facing inclined plate (.gamma.>0.deg.). Namely, an increase in the positive angle of inclination always cause the flows to be significantly more unstable. The present results are compared with the results for the parallel flow model. The nonparallel flow model has, in general, a higher critical Grashof number than does the parallel flow model. But the neutral stability curves retain their characteristic shapes.