- 면섬유에 대한 Methyl Methacrylate의 유화 그라프트 중합
- ㆍ 저자명
- 배현석,류효선,김성련,Bae. Hyun-Sook,Ryu. Hyo-Seon,Kim. Sung-Reon
- ㆍ 간행물명
- 한국의류학회지
- ㆍ 권/호정보
- 1991년|15권 3호|pp.271-280 (10 pages)
- ㆍ 발행정보
- 한국의류학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Emulsion graft copolymerization of MMA onto cotton fiber using Ce(IV) salt as an initiator was carried out. Graft yield and graft efficiency were observed according to the kinds and concentrations of emulsifier and polymerization conditions. The physical properties of MMA grafted cotton fabric were investigated. The results of this study were as follows: 1. The heighest graft yield of emulsion graft polymerization occurred at the concentration below cmc of emulsifier, which was different from emulsion polymerization. Nonionic sur- factant as an emulsifier was more effective than anionic one. 2. The highest graft yield was obtained at the initiator concentration $1{ imes}10^{-2}mol/l$. The viscometric molecular weight of PMMA was in the order of 106. 3. As reaction time increased, the graft yield increased but the graft efficiency decreased. 4. Elevation of reaction temperature resulted in increase of graft yield. The apparent activation energy of MMA graft polymerization was 4.72 Kcal/mol. 5. Physical properties of MMA grafted cotton fabric varied with increase of grafting. Thickness and stiffness showed a noticeable increase, whereas tensile strength and elongation was slightly increased. Crease recovery increased as the graft yield increase up to $50\%$ and decreased thereafter.