- Sol-Gel 법으로 제조한 알루미나 담체의 $TiO_2$ 복합 한외여과막의 특성
- ㆍ 저자명
- 현상훈,최영민
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1992년|29권 2호|pp.107-118 (12 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Alumina supports for TiO2 ultrafiltration membrane coating were prepared by presintering disk-type preforms at 140$0^{circ}C$. These supports showed uniform microstructures which had the apparent porosity of 40%, the pore size distribution in the range of 0.1~0.5${mu}{ extrm}{m}$, and the water flux of 1400ι/$m^2$.h at the pressure difference of 10 atm. The optimum pH and concentration of the TiO2 sol for coating were 0.8 and 1.0 wt%, respectively, and sol particles were identified as rutile forms of 20 nm size. Crack-free alumina-supported rutile TiO2 membranes could be prepared through well controlled drying and heating the gel layer coated by the sol-gel dipping. The pore size of the TiO2 membranes heat-treated at 50$0^{circ}C$ for 2 hrs was 30~80$AA$, and their thickness varied from 1.1 to 3.8 ${mu}{ extrm}{m}$ in accordence with the dipping time (4~40 min). The flux of water through this composite membrane at 10 atm was found to be in the range from 800 to 1100ι/$m^2$.hr depending on the dipping time (10~40 min). The membrane thickness increased linearly with the square root of the dipping time and the slope was 0.62 ${mu}{ extrm}{m}$/{{{{ SQRT { min} }}.