A recently developed new technique for measuring the fraction of wetted area has applied to pool boiling of water. The basis of the new applied technique of ultrasonic makes use of the reflection of ultrasonic from the vapour surface to measure the fraction of wetted area values. The results are the measured fraction of wetted area values in nucleate and transition boiling and the pool boiling curve for water under steady state conditions. The measurement of this paper shows a fraction of wetted areaf around 0.98 at the critical heat flux for water.