For the efficient control of photochemical smog materials, the researches on the change patterns of photochemical smog precursors are indispensable. In this study, a time-series analysis was performed for the auto-monitoring data of Kwanghwamun and Jamsil stations in 1990, and the change patterns of photochemical smog materials were studied. Especially, auto-correlation coefficients were analyzed to investigate the cyclic characteristics of pollutants in question and cross-correlation coefficients to investigate the correlations between pollutants adjusted for time lag and between $O_3$ and meteorological factors. Results of researches are as follows: First, in the case of NO and $NO_2$ intimately related to human activities, 12-hour cycle was prevalent. But $O_3$ showed 24-hour cycle. Second, NO showed a relatively high correlation with $O_3$ and usually developed into $O_3$ 5 to 7 hours later. Third, temperature, insolation intensity, and wind speed showed a positive correlation with $O_3$ while relative humidity a negative correlation.