In a bursty user traffic mode, ALOHA random multiple access protocol achieves higher performance than any conventional fixed assignment technique. One of central problems in slotted ALOHA is synchronization. Because of the long propagation delay in satellite mobile communication, packet may be spilt over into adjacent slots and thus guard time may be included between packet intervals. In conventional ALOHA channels, simultaneous transmission by two or more users results in a collision : the unsuccessful packets have to be retransmitted according to some retransmission algorithm. However, in a radio environment, users are often at different distances from the receiver : therefore, their received signals have substantially different power levels. The packet arriving with the highest energy now has a good chance of being detected accurately. Similarly, in some spread-spectrum random access systems, the earliest arriving packet dominates later arriving packets and thus captures the channel. In this paper slotted ALOHA channel with non zero guard time and capture probability is studied. Using the Markovian model, the performance of slotted ALOHA with guard time and capture effects is derived and compared with that of the conventional ALOHA via numerical analysis.