Many methods to assess hazards caused by the risks increased with the growth of petrochemical industry. The manual of International Atomic Energy Agency which was much more applied to quantitative analysis of the real situation and the CPQRA is introduced to verify the theoretical background of this manual. Than other methods, as a result, we can see that this manual, which is simple to use and requires a little information, shows similar results to those of calculation by numerical formula. Also, the program code of this manual was materialized and if it is possible to obtain adequate parameters to our circumstance, the manual will be quite useful in early risk analysis.