A solution of heat transfer problems of composite materials has been tried using homogenization technique. Homogenization technique, which was derived by applying asymptotic expansion to the standard finite element method, helped compute the equivalent thermal conductivity matrices of base cells which constituted the composite material with repeated patterns. The homogenization technique made it possible to compute the solution of the heat transfer problem of composite materials with lower degrees of freedom compared to those of other numerical methods. The equivalent thermal conductivities computed by computed by homogenization technique are also applicable to other numerical methods such as finite difference method.