A new neural network model has been developed to predict short-term air pollution concentration. In addition, a multiple regression model widely used in statistical analysis was tested. These models were applied for prediction of daily maximum ozone concentration in Seoul during the summer season of 1991. The time periods between May and September 1989 and 1990 were utilized to train set of learning patterns in neural network model, and to estimate multiple regression model. To evaluate the results of the different models, several Performance indices were used. The results indicated that the multiple regression model tended to underpredict the daily maximum ozone concentration with small r$^{2}$(0.38). Also, large errors were found in this model; 21.1 ppb for RMSE, 0.324 for NMSE, and -0.164 for MRE. On the other hand, the results obtained from the neural network model were very promising. Thus, we can know that this model has a prominent efficiency in the adaptive control for the non-linear multi- variable systems such as photochemical oxidants. Also, when the recent new information was added in the neural network model, prediction accuracy was increased. From the new model, the values of RMSE, NMSE and r$^{2}$ were 13.2ppb, 0.089, 0.003 and 0.55 respectively.