Low density polyethylene is widely used as an insulating material In electric power cables. It is most important to know the beginning of its aging by partial discharge and UV-ray. That Is reason which we investigate chemiluminescence of the LDPE treated by partial discharge, UV-ray and corona discharge. We find that it takes one hour on spectra of IR but 0.17 minutes on chemiluminescence in the variation of chemical by partial discharge. Also we knew that Lithium carbonate-added(1phr) LDPE offered obvious suppressing effect on aging by partial discharge through the chemiluminescence. Therefore, the chemiluminescence is a highly sensitive and effective measurement method to appreciate characteristics of the treated surface and the oxidation reaction.