Molecular orbital calculations at the extended Huckel level have been carried out for $Cp_2TiSiHPh(1),;[Cp_2Ti]_2[{mu}-HSi(HPh)][{mu}-H] (2),;and;[Cp_2TiSiH_2Ph]_2$ (3) complexes which are important intermediates in organosilane polymerization. Stable geometry of complex 1 is not $C_{2V}$, but Cs symmetry and the rotational energy barrier of $SiH_2$ unit is computed to be 14 kcal/mol. The orbital interaction diagrams are studied to characterize the chemical bonding for the electron deficient systems, 2 and 3. It is possible for Si-H to be coordinated to the Ti metal using $sigma$ bonding.