Fuel atomization and mixture formation in an gasoline engine has influence on the engine performance and pollutant emission. The throttle valve installed in an intake system plays a greater role in control of mixture quantity in accordance with engine drive condition. In this study, the characteristics of secondary atomization developed at the downstream of the valves were observed using an image processing method. Two major kinds of valves, solid and perforated ones, are chosen in order to compare the valve performance with the experimental parameters of air flow rate, valve opening angle, and valve shapes. For the perforated valve, we can obtain the relatively small sized droplets, and nearly uniformed and dense distributed sprays with low loss coefficient than for the solid valve.