This paper presents a method of constructing the multiple-valued combinational logic systems(MVCLS) by decision diagram. The switching function truth table of MVCLS is transformed into canonical normal form of sum-of-products(SOP) with literals at first. Next, the canonical normal form of SOP is transfered into multiple-valued logic decision diagram(MVLDD). The selecting of variable ordering is very important in this stage. The MVLDDs are quite different from each other according to the variable ordering. Sometimes the inadequate variable ordering produces a very large size of MVLDD means the large size of circuit implementation. An algorithm for generating the proper variable ordering produce minimal MVLDD and an example shows the verity of the algorithm. The circuits are realized with T-gate acceording to the minimal MVLDD.