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강대일,륭보,송정민야,Kand. Dai-Ill,Takayasu.. A.Koezuka,Tosiya. Matsui
간행물명
保存科學硏究
권/호정보
1995년|16권 |pp.59-111 (53 pages)
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국립문화재연구소
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Chemical composion and crystal form of Corrosion products found on archaeological iron objects were analyzed using X-ray fluorescence analysis, micro-X-ray powder diffraction analysis and ion chromatographic technique. The nature and behavior of the corrosion products were studied in order to aid in the conservation and restoration of burial iron objects. Twenty-two samples analyzed in this study were collected from iron object found in Korea and Japan. The corrosion products of iron objects from burial mounds contain $alpha$-FeOOH, $eta$-FeOOH, $gamma$-FeOOH, $Fe_3O_4$and amorphous iron hydroxides. The content of $alpha$-HeOOH is the greatest. Because, Ageing for long period should change the amorphous iron hydroxides is considerably less than that in usual atmospheric corrosion products. The concentration of chlorine and sulfine is remarkably variable ($Cl^-$ : 100- 30,000ppm, $SO_4^-2$ : 20-10,000ppm),but the reasons are unclear. The presence of generally high concentrations of chlorine and sulfine the corrosion products of iron objects seem to be influenced by the marine climatic condition. The presence of high chlorine and sulfine concentrations in the corrosion products of iron objects seem to be influenced by the marine burial environments.