- 고대 철기유물의 부식 생성물에 관한 연구
- ㆍ 저자명
- 강대일,륭보,송정민야,Kand. Dai-Ill,Takayasu.. A.Koezuka,Tosiya. Matsui
- ㆍ 간행물명
- 保存科學硏究
- ㆍ 권/호정보
- 1995년|16권 |pp.59-111 (53 pages)
- ㆍ 발행정보
- 국립문화재연구소
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Chemical composion and crystal form of Corrosion products found on archaeological iron objects were analyzed using X-ray fluorescence analysis, micro-X-ray powder diffraction analysis and ion chromatographic technique. The nature and behavior of the corrosion products were studied in order to aid in the conservation and restoration of burial iron objects. Twenty-two samples analyzed in this study were collected from iron object found in Korea and Japan. The corrosion products of iron objects from burial mounds contain $alpha$-FeOOH, $eta$-FeOOH, $gamma$-FeOOH, $Fe_3O_4$and amorphous iron hydroxides. The content of $alpha$-HeOOH is the greatest. Because, Ageing for long period should change the amorphous iron hydroxides is considerably less than that in usual atmospheric corrosion products. The concentration of chlorine and sulfine is remarkably variable ($Cl^-$ : 100- 30,000ppm, $SO_4^-2$ : 20-10,000ppm),but the reasons are unclear. The presence of generally high concentrations of chlorine and sulfine the corrosion products of iron objects seem to be influenced by the marine climatic condition. The presence of high chlorine and sulfine concentrations in the corrosion products of iron objects seem to be influenced by the marine burial environments.