The properties of FRP(fiber-reinforced plastics) depend not only on the characteristics of the matrix but also on the structure of fiber mat and the fiber type of reinforcement. Therefore it is very important to study the characteristics of reinforcement and matrix. In this paper, a method is proposed which can be used to measure the mean coeffcient of separation for the press molding of FRP, and the mean equivalent coefficient of separation is obtained from the separation coefficient. And the relationship between the mean equivalent coefficient of separation and the structure of fiber mat is discussed. The effects of corrlelation coefficient between separation and orientation on the mean equivalent coefficient are also presented.