- 고흡수성 재료로서 셀룰로오스계 그라프트 고분자의 제조(I) - 저치환 시아노에틸화 목재 펄프와 아크릴아미드의 공중합 -
- ㆍ 저자명
- 문성필,김재필
- ㆍ 간행물명
- 韓國纖維工學會誌
- ㆍ 권/호정보
- 1996년|33권 8호|pp.715-721 (7 pages)
- ㆍ 발행정보
- 한국섬유공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Super water absorbents were prepared by graft copolymerization of acrylamide(AM) monomer onto the low cyanoethylated wood pulp(LCE-WP) having degree of substitution(D.S.) 0.13, 0.35 and 0.63 followed by alkaline hydrolysis. The copolymerization rate of AM onto the LCE-WP of D.S. 0.13 and D.S. 0.35 were similar, while the LCE-WP of D.S. 0.63 showed faster copolymerization rate than the other two LCE-WPs. The degree of hydrolysis of super water absorbents was in the range of 60-85%. H-LCE-WP-g-PAM obtained by alkaline hydrolysis of the grafted LCE-WPs showed higher absorbency than that of WP. The H-LCE-WP-g-PAM prepared from the LCE-WP of D.S. 0.35 having graft yield of 290% exhibited the largest absorbencies of 5400 g/g for water and 75 g/g for 0.9% NaCl solution, respectively. Their absorbencies were about twice as much as those of the super water absorbent from WP.