- 반도성 <tex>$BaTiO_3$</tex> 세라믹스의 Sol-gel법에 의한 <tex>$SiO_2$</tex> 첨가 및 냉각속도 효과
- ㆍ 저자명
- 권오성,정용선,윤영호,이병하
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1996년|33권 12호|pp.1301-1310 (10 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Generally it requires high sintering temperatures more than 135$0^{circ}C$ to make semiconductive BaTiO3 ceramics. Also it is very difficult to achieve a homogeneous mixing in solid-state reaction method. Therefore the liquid phase distributed to non-uniform dilute the characteristics of PTCR. In order to improve the uniformity this study is used the sol-gel coating method. Using this method we studied the new manufacturing process that had a high reproducibility and mass production capability. Tetraethyl orthosilicate (TEOS) was used as a source of Si. The semiconductive BaTiO3 ceramics which was produced by sol-gel method for the SiO2 addition and sintered between 124$0^{circ}C$ and 130$0^{circ}C$ showed almost same resistivity at room temperature among 125$0^{circ}C$ and 130$0^{circ}C$. As the results We could be sintered the semiconducting BaTiO3 ceramics at lower temperature even at 125$0^{circ}C$ maintaining the same specific resistivity ratio ($ ho$max/$ ho$min) at 130$0^{circ}C$. The specific resistivity both below and above the Curie temperature were increased by slow cooling and the steepness of the plots in the reasion of transition from low to high resistance increased as the cooling rate decreased.