Instantaneous surface temperature and unsteady heat flux of intake and exhaust valve in methanol fueled engine were investigate as a function of compression ratio and engine speed. To accomplish this purpose, the instantaneous temperature sensor was designed and it was installed into three point of intake and exhaust valve head to measure unsteady temperature. The unsteady heat flux at valves was evaluated using one dimensional heat conduction equation with the valve head temperature and temperature gradient. And also mean heat flux of intake and exhaust valve for each stroke were evaluated as a function of engine speed.