In this research, we use IDI type constant volume combustion chamber which may make up stratified combustion to construct the design back data of lean-burn engine. Some experiments are conducted by the passagehole angle in the adapter of main chamber and sub-chamber. The effects on the combustion characteristics according to the ignition timing are investigated. The used fuel is methanol prospective for alternative fuel. Fuel is injected under 10.78MPa using solenoid and accumulator. As the results of the experiment, combustion characteristics reveals that ignition timing, passagehole angle and shape greatly effects on. Lean inflammability limit is extended to 0.45 in equivalence ratio.