The bit error probability of RS/trellis concatenated coded-modualtion system in the mobile radio channel is analyzed. A new upper bound to the symbol error probability of the inner TCM in the mobile radio channel is obtained by exploiting the unequal symbol error probability of the TCM. This bound is applied to the derivation of the upper bound to the bit error probability of the concatenated coded-modulation system. An efficient way of searching distance spectrum of the TCM in mobile radio channel is devised. Our new bounds are tighter than the earlier studied other bounds.