The purpose of this study is to investigate the break-up characteristics by taking advantage of a two-phase coaxial nozzle. Air and water are utilized as working fluids and the mass ratio air/water has been controlled to characterize the atomization, diffusion and development of mixing process. By way of a photographic technique, conventional developing structures and diffusion angles have been analyzed systematically with variations of mass ratios. The turbulent flow components of the atomized particles were measured by a two channel LDV system and the data were treated by an on-lined measurement equipment. According to the photographic results the spreading angles decreased because the axial inertia moment was relatively higher than the lateral one with respect to the increase of mass ratio. It is found the jet flow diffuses linearly in a certain limit region while the atomizing characteristics, in terms of the distributions of particle diameters did not show particular differences. It may be expected that these fundamental results can be used as reference data in studying the atomization, breakup and diffusions.