- 내충격성 폴리스티렌의 고무상 입자경 예측
- ㆍ 저자명
- 이성재,정경호,Lee. Seong-Jae,Chung. Kyung-Ho
- ㆍ 간행물명
- 고무學會誌
- ㆍ 권/호정보
- 1996년|31권 5호|pp.327-334 (8 pages)
- ㆍ 발행정보
- 한국고무학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
A correlative analysis has been carried out to predict the average particle size of rubber dispersed phase In high impact polystyrene manufactured by bulk polymerization. To do the correlation, a mechanistic model suggested previously by the author was used for describing the size of stabilizing particles agitated under the turbulent viscous shear subranges in a prepolymerization reactor, where the rubber particles were assumed to be formed at the time of phase inversion in the reactor. Viscosities required for the model were postulated to describe the overall behavior of butadiene rubber and polystyrene mixture along the wide range of conversion. The good agreement between the model and the experimental data from a plant was quite satisfactory for the prediction of the average rubber particle size of high impact polystyrene.