- EPDM/PP/Ionomer 삼원 블렌드로 된 열가소성 가황체의 파괴 인성
- ㆍ 저자명
- 김영규,조원제,하창식,고진환,Kim. K.,Cho. W.J.,Ha. C.S.,Go. J.H.
- ㆍ 간행물명
- 고무學會誌
- ㆍ 권/호정보
- 1996년|31권 5호|pp.341-346 (6 pages)
- ㆍ 발행정보
- 한국고무학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The fracture mechanics investigation of the thermoplastic vulcanizates(TPV) from EPDM and PP/Ionomer ternary blends was performed in terms of the J-integral by measuring fracture energy via the locus method. The TPV from ternary blends consisting of EPDM, PP and ionomer were prepared in a laboratory integral mixer by blending and vulcanizing simultaneously. Vulcanization was performed with dicumyl peroxide (DCP) and the composition of EPDM and PP was fixed at 50/50 by weight. Two kinds of poly(ethylene-co-methacrylic acid) (EMA) lonomers were used. The J-integral values at crack initiation, Jc, of the dynamically vulcanized EPDM and PP/EMA Ionomer ternary blends were affected by the cation types $(Na^+;or;Zn^{2+})$ and contents(5-20wt%) of the added EMA Ionomers. The ternary blend containing 20wt% zinc-neutralized EMA Ionomer and 1.0phr DCP showed the highest Jc values of the blends.