Simultaneous monitoring in many locations is necessary to evaluate the air quality and analyze future trend of a city, For this purpose, it is essential to install air pollution monitoring network. The first automatic air pollution monitoring network was introduced Seoul in 1973. As of 1995, 20 monitoring stations are now in operation. Concerning the management of the air pollution monitoring network, there was some argument among the relavant scholars, non-governmental organization(NGO) and the government organization. So far, there was no extensive evaluation and analysis about the network. The purpose of this study was to evaluate the representativeness of air quality monitoring network through actual measurement of the concentration of the air pollutant. The concentration of NOx was extensively measured widely in Seoul area three times using the TEA simple measuring technique. Even the judgement level for the area representativeness was lowered to 80%, Ssangmun-dong monitoring station tend to overestimate the pollutant concentration of the covered area. While, Sinlimdong monitoring station tend to underestimate the pollutant concentration of the covered area.